Hydrology Program

Publications on Surfactant-Modified Zeolite
Robert S. Bowman, Professor of Hydrology


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          Link to List of SMZ Abstracts

Refereed Publications in Journals

Simpson, J.A. and R.S. Bowman. 2009. Nonequilibrium sorption and transport of volatile petroleum hydrocarbons in surfactant-modified zeolite, J. Contam. Hydrol. 108(1-2):1-11, doi:10.1016/j.jconhyd.2009.05.001.
Altare, C.R., R.S. Bowman, L.E. Katz, K.A. Kinney, and E.J. Sullivan. 2007. Regeneration and long-term stability of surfactant-modified zeolite for removal of volatile organic compounds from produced water. Microporous Mesoporous Mat. 105:305-316, doi:10.1016/j.micromeso.2007.04.001. [Abstract]
Zhang, P., D.M. Avudzega, and R.S. Bowman. 2007. Removal of perchlorate from contaminated waters using surfactant-modified zeolite. J. Environ. Qual. 36:1069–1075, doi:10.2134/jeq2006.0432. [Abstract]
Li, Z., H.K. Jones, P. Zhang, and R.S. Bowman. 2007. Chromate transport through columns packed with surfactant-modified zeolite/zero-valent-iron pellets. Chemosphere 68:1861-1866, doi:10.1016/j.chemosphere.2007.03.011. [Abstract]
Li, Z., C. Willms, J. Alley, P. Zhang, and R.S. Bowman. 2006. A shift in pathway of iron-mediated perchloroethylene reduction in the presence of sorbed surfactant—a column study, Water Res. 40:3811-3819, doi:10.1016/j.watres.2006.08.025. [Abstract]
Burt, T.A., Z. Li, and R.S. Bowman. 2005. Evaluation of granular surfactant-modified zeolite/zero valent iron pellets as a reactive material for perchloroethylene reduction. J. Environ. Eng. 131:934-942. [Abstract]
Faghihian, H., and R.S. Bowman. 2005. Adsorption of chromate by clinoptilolite exchanged with various metal cations. Water Res. 39:1099-1104. doi:10.1016/j.watres.2004.12.010 [Abstract]
Karapanagioti, H.K., D.A. Sabatini, and R.S. Bowman. 2005. Partitioning of hydrophobic organic chemicals (HOC) into anionic and cationic surfactant-modified sorbents. Water Res. 39(4):699-709. doi:10.1016/j.watres.2004.10.014 [Abstract]

Burt, T.A., Z. Li, and R.S. Bowman. 2005. Evaluation of granular surfactant-modified zeolite/ zero valent iron pellets as a reactive material for perchloroethylene reduction. J. Environ. Eng. 131(6):934-942. doi:10.1061/(ASCE)0733-9372(2005)131:6(934). [Abstract]

Ranck, J.M., R.S. Bowman, J.L. Weeber, L.E. Katz, and E.J. Sullivan. 2005. BTEX removal from produced water using surfactant-modified zeolite. J. Environ. Eng. 131(3):434-442. doi:10.1061/(ASCE)0733-9372(2005)131:3(434) [Abstract]
Barker, J.M., P.S. Freeman, G.S.Austin, and R.S. Bowman. 2004. Development of value-added zeolite products from St Cloud Mining. CIM Bulletin 97:52-58. [Abstract]
Zhang, P., J. Šimunek, and R.S. Bowman. 2004. Nonideal transport of solute and colloidal tracers through reactive zeolite/iron pellets. Water Resour. Res., 40(4):W04207, doi:10.1029/2003WR002445. [Abstract]
Li, Z., C. Willms, S. Roy, and R.S. Bowman 2003. Desorption of hexadecyltrimethylammonium from charged mineral surfaces. Environ. Geosci. 10:37-45. PDF (272KB)
Sullivan, E.J., R.S. Bowman, and I.A. Legiec. 2003. Sorption of arsenate from soil-washing leachate by surfactant-modified zeolite. J. Environ. Qual. 32:2387-2391. [Abstract]
Schulze-Makuch, D., R.S. Bowman, S. D. Pillai, and H. Guan. 2003. Field evaluation of the effectiveness of surfactant modified zeolite and iron-oxide-coated sand for removing viruses and bacteria from ground water. Ground Water Monitoring and Remediation 23(4):68-74. [Abstract]
Bowman, R.S. 2003. Applications of surfactant-modified zeolites to environmental remediation. Microporous Mesoporous Mat. 61:43-56. [Abstract]
Zhang, P., X. Tao, Z. Li, and R.S. Bowman. 2002. Enhanced perchloroethylene reduction in column systems using surfactant-modified zeolite/zero-valent iron pellets. Environ. Sci. Technol. 36:3597-3603.
doi:10.1021/es015816u. [Abstract]
Schulze-Makuch, D., D. Pillai, S.D., Guan, H., Bowman, R. Couroux, E., Hielscher, F., Totten, J., Espinosa, I.Y., Kretzschmar, T. 2002. Surfactant-modified zeolite can protect drinking water wells from viruses and bacteria. EOS 83:193-201.
Li, Z., Alessi, D., Zhang, P., and R.S. Bowman. 2002. Organo-illite as a low permeability sorbent to retard migration of anionic contaminants. J. Environ. Eng. 128(7):583-587. doi:10.1061/(ASCE)0733-9372(2002)128:7(583) [Abstract]
Li, Z., and R.S. Bowman. 2001. Retention of inorganic oxyanions by organo-kaolinite. Water Research 35: 3771-3776. doi:10.1016/S0043-1354(01)00120-8 [Abstract]
Li, Z., and R.S. Bowman. 2001. Regeneration of surfactant-modified zeolite after saturation with chromate and perchloroethylene. Water Research. 35:322-326. doi:10.1016/S0043-1354(00)00258-X [Abstract]
Li, Z., T. Burt, and R. S. Bowman. 2000. Sorption of ionizable organic solutes by surfactant-modified zeolite. Environ. Sci. Technol. 34:3756-3760. doi:10.1021/es990743o [Abstract]
Li, Z, H.K. Jones, R.S. Bowman, and R. Helferich. 1999. Enhanced reduction of chromate and PCE by pelletized surfactant-modified zeolite/zero valent iron. Environ. Sci. Technol. 33:4326-4330. doi:10.1021/es990334s [Abstract]
Sullivan, E.J., J.W. Carey, and R.S. Bowman.  1998.  Thermodynamics of cationic surfactant sorption onto natural clinoptilolite. J. Colloid Interface Sci. 206:369-380. doi:10.1006/jcis.1998.5764 [Abstract]
Li, Z., and R.S. Bowman.  1998.  Sorption of chromate and PCE by surfactant-modified clay minerals.  Environ. Eng. Sci.15:237-245.
Li, Z., I. Anghel, and R.S. Bowman. 1998. Sorption of oxyanions by surfactant-modified zeolite. J. Dispersion Sci. Technol. 19:843-857.
Li, Z., S. Roy, and R.S. Bowman. 1998. Long term chemical and biological stability of surfactant-modified zeolite. Environ. Sci. Technol. 32:2628-2632. doi:10.1021/es970841e [Abstract]
Li, Z., and R.S. Bowman. 1998. Density-controlled partitioning mechanism for sorption of perchloroethylene by surfactant- modified zeolite. Environ. Sci. Technol. 32:2278-2282. doi:10.1021/es971118r [Abstract]
Sullivan, E.J., D.B. Hunter, and R.S. Bowman. 1998. Fourier- transform Raman spectroscopy of sorbed HDTMA and the mechanism of chromate sorption to surfactant-modified clinoptilolite. Environ. Sci. Technol. 32:1948-1955. doi:10.1021/es9708981 [Abstract]
Li, Z., and R.S. Bowman. 1997. Counterion effects on the sorption of cationic surfactant and chromate on natural clinoptilolite. Environ. Sci. Technol. 31:2407-2412. doi:10.1021/es9610693 [Abstract]
Sullivan, E.J., D.B. Hunter, and R.S. Bowman. 1997. Topological and thermal properties of surfactant-modified clinoptilolite studied by tapping-mode atomic force microscopy and high-resolution thermogravimetric analysis. Clays Clay Min. 45:42-53.
Haggerty, G.M., and R.S. Bowman. 1994. Sorption of inorganic anions by organo-zeolites. Environ. Sci. Technol. 28(3):452-458.

  Book Chapters
Bowman R.S., Z. Li, S. J. Roy, T. Burt, T.L. Johnson, and R.L. Johnson. 2001. Pilot test of a surfactant-modified zeolite permeable barrier for groundwater remediation. p. 161-185.  In J.A. Smith and S. Burns, (eds.). Physical and chemical remediation of contaminated aquifers. Kluwer Academic Publishers.
Bowman, R.S., E.J. Sullivan, and Z. Li.  2000. Uptake of cations, anions, and nonpolar organic molecules by surfactant-modified clinoptilolite-rich tuff. p. 287-297.  In C. Colella and F.A Mumpton  (eds.) Natural zeolites for the third millenium.  De Frede Editore, Naples, Italy.
Bowman, R.S., G.M. Haggerty, R.G. Huddleston, D. Neel, and M. Flynn. 1995. Sorption of nonpolar organics, inorganic cations, and inorganic anions by surfactant-modified zeolites. p. 54-64. In D.A. Sabatini, R.C. Knox, and J.H. Harwell (eds.). Surfactant- enhanced remediation of subsurface contamination. ACS Symposium Series 594. American Chemical Society, Washington, DC.

Patents

Schulze-Makuch, D., R.S. Bowman, and S. Pillai. 2003. Removal of biological pathogens using surfactant-modified zeolite. Patent pending.

Bowman, R.S. and R. Helferich.  2001.  Production and article of iron/surfactant-modified zeolite pellets to retain and destroy water pollutants.  Patent No.: US 6,261,986 B1. Date of Patent: Jul. 17, 2001.
 

Symposia Proceedings

Darby, E.B., L. Katz, K. Kinney, R. Bowman, and E. Sullivan. 2006. Assessment of a surfactant-modified zeolite/vapor phase biofilter process for treating produced water. In Proc. Texas Section American Society of Civil Engineers, 11-14 October 2006, San Antonio, TX.

Bowman, R.S. 2004. Surfactant-modified zeolites for remediation of contaminated groundwater. In Proc. International Symposium on Hydrogeological Investigation and Remedial Technology, 15-16 November 2004, Jhongli, Taiwan, ROC.

Ranck, J.M., J.L. Weeber, G. Tan, E.J. Sullivan, L.E. Katz, and R.S. Bowman. 2002. Removal of BTEX from produced waters using surfactant-modified zeolite. In Proc. Ninth Ann. International Petroleum Environmental Conf., 22-25 October 2002, Albuquerque, NM.

Austin G.S., and R.S. Bowman. 2002. St. Cloud Mining Company’s Stone House zeolite mine and new uses for clinoptilolite. In Proc. Society for Mineral Engineering National Meeting, 25-27 February 2002, Phoenix, AZ.

Fuierer, A.M, R.S. Bowman, and T.L. Kieft. 2001. Biodegradation of toluene sorbed to surfactant-modified zeolite. Proc. Sixth International Symp. on In Situ and On-Site Bioremediation, 4-7 June 2001, San Diego, CA.

Bowman, R. S., Z. Li, S. J. Roy, T. A. Burt, R. L. Johnson, and T. L. Johnson. 1999. A pilot-scale test of a surfactant-modified zeolite permeable barrier. p. 37-41. In Proc. WERC Conf. On the Environment, 26-29 April 1999, Albuquerque, NM.

Burt, T. A., H. K. Jones, Z. Li, R. S. Bowman, and R. Helferich. 1999. Perchloroethylene and chromate reduction using a surfactant-modified zeolite/ zero-valent iron pellet. p. 231-235. In Proc. WERC Conf. On the Environment, 26-29 April 1999, Albuquerque, NM.

Bowman, R.S., Roy, S.J., Li, Z., Johnson, R.L., and Johnson, T.L.  1998.  A pilot-scale test of a surfactant-modified zeolite permeable barrier. p. 231-236. In Proc. RTDF Permeable Barriers Action Team Meeting, 15-16 April 1998, Beaverton, OR.

Roy, S.J., Z. Li, K. Hildenbrand, R.S. Bowman, R.L. Johnson, T.L. Johnson, and M. Perrott.  1998. A surfactant-modified zeolite permeable barrier for the remediation of chrome and PCE:  Pilot study results.  p. 271-275.  In Proc. WERC-WRHSRC-NMHWMS ‘98 Joint Conf. On the Environment, 31 March-1 April 1998, Albuquerque, NM.

Jones, H.K., Z. Li, R.S. Bowman, and R. Helferich.  1998.  Reduction of dissolved perchloroethylene by pelletized zero-valent iron/surfactant-modified zeolite.  p. 3-7.  In Proc. WERC-WRHSRC-NMHWMS ‘98 Joint Conf. On the Environment, 31 March-2 April 1998, Albuquerque, NM.

Li, Z., T. Burt, and R.S. Bowman.  1998.  Sorption of benzene, phenol, and aniline by surfactant-modified zeolite.  p. 277-281.  In Proc. WERC-WRHSRC-NMHWMS ‘98 Joint Conf. On the Environment, 31 March-2 April 1998, Albuquerque, NM.

Bowman, R.S., E.J. Sullivan, and Z. Li. 1997. Mechanisms of contaminant sorption by surfactant-modified zeolite. p. 104-108. In Proc. WERC/HSRC '97 Joint Conference on the Environment, 22-24 April 1997, Albuquerque, NM.

Li, Z., H.K. Jones, R.S. Bowman, and R. Helferich. 1997. Incorporation of zero valent iron into pelletized surfactant- modified zeolite for groundwater remediation. p. 463-467. In Proc. WERC/HSRC '97 Joint Conference on the Environment, 22-24 April 1997, Albuquerque, NM.

Anghel, I., J. Whitworth, S. Roy, and R.S. Bowman. 1997. Remediation of subsurface chromium (VI) and PCE contamination with surface-modified zeolites: saturated column studies. p. 468- 472. In Proc. WERC/HSRC '97 Joint Conference on the Environment, 22-24 April 1997, Albuquerque, NM.

Bowman, R.S. 1996. Surfactant-altered zeolites as permeable barriers for in situ treatment of contaminated groundwater. In Proc. Industry Partnerships to Deploy Environmental Technology Meeting, 22-24 October 1996, Morgantown, WV. 41 p.

Bowman, R.S., E.J. Sullivan, and G. Li. 1996. Surfactant-modified zeolites as sorbents for cationic and anionic metals. p.702-704. In Emerging Technologies in Hazardous Waste Management VIII. Industrial & Engineering Chemistry Division, American Chemical Society National Meeting, 9-12 Sept. 1996, Birmingham, AL. American Chemical Society, Washington, DC. 

Bowman, R.S., and E.J. Sullivan. 1995. Surfactant-modified zeolites as permeable barriers to organic and inorganic groundwater contaminants. p. 392-397. In Proc. Environmental Technol. Develop. through Industry Partnership Conf., Vol II, 3-5 October 1995, Morgantown, WV.

Teppen, B.J., D.B. Hunter, P.M. Bertsch, E.J. Sullivan, and R.S. Bowman. 1995. Modeling organic modification of a natural zeolite surface. p. 181-184. In Preprints of Papers, American Chemical Society Annual Meeting, 20-24 August 1995, Chicago, IL.

Sullivan, E.J., R.S. Bowman, and G.M. Haggerty. 1994. Sorption of inorganic oxyanions by surfactant-modified zeolites. p. 940- 945. In Proc. SPECTRUM '94, Nuclear and Hazardous Waste Topical Mtg., 14-18 August 1994, Atlanta, GA.

Cadena, F., and R.S. Bowman. 1994. Treatment of waters contaminated with BTX and heavy metals using tailored zeolites. p. 297-310. In Proc. 4th Annual WERC Technology Development Conf., 13-15 April 1994, Las Cruces, NM.

Bowman, R.S., M. Flynn, G.M. Haggerty, R.G. Huddleston, and D. Neel. 1993. Organo-zeolites for sorption of nonpolar organics, inorganic cations, and inorganic anions. p. 1103-1109. In Proc. Joint CSCE-ASCE National Conference on Environmental Engineering, 12-14 July 1993, Montreal, Quebec, Canada.

Neel, D., and R.S. Bowman. 1992. Sorption of organics to surface-altered zeolites. p. 57-61. In Proc. 36th Annual New Mexico Water Conf., 7-8 November 1991, Las Cruces, NM.
 

Research Reports

Bowman, R.S., P.Zhang, X. Tao, R.L. Johnson, and D. Wolf. 2002. Surface-altered zeolites as permeable barriers for in situ treatment of contaminated groundwater. Phase IIB Topical Report. U.S. Department of Energy, National Energy Technology Laboratory, Pittsburgh, PA. 33 p. Download PDF (2.4 MB)

Bowman, R.S., Z. Li, S.J. Roy, T. Burt, T.L. Johnson, and R.L. Johnson. 1999. Surface-altered zeolites as permeable barriers for in situ treatment of contaminated groundwater. Phase II Topical Report. U.S. Department of Energy, Office of Environmental Management, Pittsburgh, PA. 49 p. Download PDF (2.3 MB)

Bowman, R.S. 1996. Surface-altered zeolites as permeable barriers for in situ treatment of contaminated groundwater. Phase I Topical Report. U.S. Department of Energy, Office of Environmental Management, Morgantown, WV. 40 p. Download PDF (7.4 KB)


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Last Updated: August 26, 2009